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<span id="openzim-page-title" class="mw-page-title-main"><span class="mw-page-title-main">Mineral evolution</span></span>
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<p><b>Mineral evolution</b> is a recent <a href="Hypothesis" title="Hypothesis">hypothesis</a> that provides historical context to <a href="Mineralogy" title="Mineralogy">mineralogy</a>. It postulates that mineralogy on planets and moons becomes increasingly complex as a result of changes in the physical, chemical and biological environment. In the <a href="Solar_System" title="Solar System">Solar System</a>, the number of <a href="Mineral_species" class="mw-redirect" title="Mineral species">mineral species</a> has grown from about a dozen to over 5400 as a result of three processes: separation and concentration of elements; greater ranges of temperature and pressure coupled with the action of volatiles; and new chemical pathways provided by living organisms.
</p><p>On Earth, there were three eras of mineral evolution. The birth of the Sun and formation of asteroids and planets increased the number of minerals to about 250. Repeated reworking of the <a href="Crust_(geology)" title="Crust (geology)">crust</a> and <a href="Mantle_(geology)" title="Mantle (geology)">mantle</a> through processes such as partial melting and <a href="Plate_tectonics" title="Plate tectonics">plate tectonics</a> increased the total to about 1500. The remaining minerals, more than two-thirds of the total, were the result of chemical changes mediated by living organisms, with the largest increase occurring after the <a href="Great_Oxygenation_Event" class="mw-redirect" title="Great Oxygenation Event">Great Oxygenation Event</a>.
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<div class="mw-heading mw-heading2"><h2 id="Use_of_the_term_"evolution"">Use of the term "evolution"</h2></div>
<p>In the 2008 paper that introduced the term "mineral evolution", <a href="Robert_Hazen" title="Robert Hazen">Robert Hazen</a> and co-authors recognized that an application of the word "evolution" to minerals was likely to be controversial, although there were precedents as far back as the 1928 book <i>The Evolution of the Igneous Rocks</i> by <a href="Norman_L._Bowen" title="Norman L. Bowen">Norman Bowen</a>. They used the term in the sense of an irreversible sequence of events leading to increasingly complex and diverse assemblages of minerals.<sup id="cite_ref-urPaper_1-0" class="reference"><a href="#cite_note-urPaper-1"><span class="cite-bracket">[</span>1<span class="cite-bracket">]</span></a></sup> Unlike <a href="Evolution" title="Evolution">biological evolution</a>, it does not involve <a href="Mutation" title="Mutation">mutation</a>, <a href="Competition_(biology)" title="Competition (biology)">competition</a> or <a href="Heredity" title="Heredity">passing of information to progeny</a>. Hazen et al. explored some other analogies, including the idea of <a href="Extinction" title="Extinction">extinction</a>. Some mineral-forming processes no longer occur, such as those that produced certain minerals in <a href="Enstatite_chondrite" title="Enstatite chondrite">enstatite chondrites</a> that are unstable on Earth in its oxidized state. Also, the <a href="Runaway_greenhouse_effect" title="Runaway greenhouse effect">runaway greenhouse effect</a> on <a href="Venus" title="Venus">Venus</a> may have led to permanent losses of mineral species.<sup id="cite_ref-urPaper_1-1" class="reference"><a href="#cite_note-urPaper-1"><span class="cite-bracket">[</span>1<span class="cite-bracket">]</span></a></sup><sup id="cite_ref-complexity_2-0" class="reference"><a href="#cite_note-complexity-2"><span class="cite-bracket">[</span>2<span class="cite-bracket">]</span></a></sup> However, mineral extinction is not truly irreversible; a lost mineral could emerge again if suitable environmental conditions were re-established.<sup id="cite_ref-Rosing_3-0" class="reference"><a href="#cite_note-Rosing-3"><span class="cite-bracket">[</span>3<span class="cite-bracket">]</span></a></sup>
</p>
<div class="mw-heading mw-heading2"><h2 id="Presolar_minerals">Presolar minerals</h2></div>
<p>In the early Universe, there were no minerals because the only elements available were <a href="Hydrogen" title="Hydrogen">hydrogen</a>, <a href="Helium" title="Helium">helium</a> and trace amounts of <a href="Lithium" title="Lithium">lithium</a>.<sup id="cite_ref-4" class="reference"><a href="#cite_note-4"><span class="cite-bracket">[</span>4<span class="cite-bracket">]</span></a></sup> Mineral formation became possible after heavier elements, including <a href="Carbon" title="Carbon">carbon</a>, oxygen, <a href="Silicon" title="Silicon">silicon</a> and <a href="Nitrogen" title="Nitrogen">nitrogen</a>, were synthesized in stars. In the expanding atmospheres of <a href="Red_giant" title="Red giant">red giants</a> and the ejecta from <a href="Supernova" title="Supernova">supernovae</a>, microscopic minerals formed at temperatures above 1,500 °C (2,730 °F).<sup id="cite_ref-urPaper_1-2" class="reference"><a href="#cite_note-urPaper-1"><span class="cite-bracket">[</span>1<span class="cite-bracket">]</span></a></sup><sup id="cite_ref-McCoy_5-0" class="reference"><a href="#cite_note-McCoy-5"><span class="cite-bracket">[</span>5<span class="cite-bracket">]</span></a></sup>
</p><p>Evidence of these minerals can be found in interstellar grains incorporated into primitive <a href="Meteorite" title="Meteorite">meteorites</a> called <a href="Chondrite" title="Chondrite">chondrites</a>, which are essentially cosmic sedimentary rocks.<sup id="cite_ref-McCoy_5-1" class="reference"><a href="#cite_note-McCoy-5"><span class="cite-bracket">[</span>5<span class="cite-bracket">]</span></a></sup> The number of known species is roughly a dozen, although several more materials have been identified but not classified as minerals.<sup id="cite_ref-McCoy_5-2" class="reference"><a href="#cite_note-McCoy-5"><span class="cite-bracket">[</span>5<span class="cite-bracket">]</span></a></sup> Because it has a high crystallization temperature (about 4,400 °C (7,950 °F)), <a href="Diamond" title="Diamond">diamond</a> was probably the first mineral to form.<sup id="cite_ref-Hadean_6-0" class="reference"><a href="#cite_note-Hadean-6"><span class="cite-bracket">[</span>6<span class="cite-bracket">]</span></a></sup><sup id="cite_ref-7" class="reference"><a href="#cite_note-7"><span class="cite-bracket">[</span>7<span class="cite-bracket">]</span></a></sup> This was followed by <a href="Graphite" title="Graphite">graphite</a>, <a href="Oxide" title="Oxide">oxides</a> (<a href="Rutile" title="Rutile">rutile</a>, <a href="Corundum" title="Corundum">corundum</a>, <a href="Spinel" title="Spinel">spinel</a>, <a href="Hibonite" title="Hibonite">hibonite</a>), <a href="Carbide" title="Carbide">carbides</a> (<a href="Moissanite" title="Moissanite">moissanite</a>), <a href="Nitride" title="Nitride">nitrides</a> (<a href="Osbornite" title="Osbornite">osbornite</a> and <a href="Silicon_nitride" title="Silicon nitride">silicon nitride</a>) and <a href="Silicate_minerals" class="mw-redirect" title="Silicate minerals">silicates</a> (<a href="Forsterite" title="Forsterite">forsterite</a> and <a href="Silicate_perovskite" title="Silicate perovskite">silicate perovskite</a> (MgSiO<sub>3</sub>)).<sup id="cite_ref-urPaper_1-3" class="reference"><a href="#cite_note-urPaper-1"><span class="cite-bracket">[</span>1<span class="cite-bracket">]</span></a></sup> These "ur-minerals" seeded the molecular clouds from which the Solar system was formed.<sup id="cite_ref-Condie_8-0" class="reference"><a href="#cite_note-Condie-8"><span class="cite-bracket">[</span>8<span class="cite-bracket">]</span></a></sup>
</p>
<div class="mw-heading mw-heading2"><h2 id="Processes">Processes</h2></div>
<p>After the formation of the Solar system, mineral evolution was driven by three primary mechanisms: the separation and concentration of elements; greater ranges of temperature and pressure combined with chemical action of volatiles; and new reaction pathways driven by living organisms.<sup id="cite_ref-9" class="reference"><a href="#cite_note-9"><span class="cite-bracket">[</span>9<span class="cite-bracket">]</span></a></sup>
</p>
<div class="mw-heading mw-heading3"><h3 id="Separation_and_concentration">Separation and concentration</h3></div>
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</style><div role="note" class="hatnote navigation-not-searchable">See also: <a href="Geochemistry#Differentiation_and_mixing" title="Geochemistry">Geochemistry § Differentiation and mixing</a></div>
<p>The highest level in the classification of minerals is based on chemical composition.<sup id="cite_ref-Jolyon_10-0" class="reference"><a href="#cite_note-Jolyon-10"><span class="cite-bracket">[</span>10<span class="cite-bracket">]</span></a></sup> However, the defining elements for many mineral groups, such as <a href="Boron" title="Boron">boron</a> in <a href="Borate_minerals" class="mw-redirect" title="Borate minerals">borates</a> and <a href="Phosphorus" title="Phosphorus">phosphorus</a> in <a href="Phosphate_minerals" class="mw-redirect" title="Phosphate minerals">phosphates</a>, were at first only present in concentrations of parts per million or less. This left little or no chance for them to come together and form minerals until external influences concentrated them.<sup id="cite_ref-HazenAeon_11-0" class="reference"><a href="#cite_note-HazenAeon-11"><span class="cite-bracket">[</span>11<span class="cite-bracket">]</span></a></sup> Processes that separate and concentrate elements include <a href="Planetary_differentiation" title="Planetary differentiation">planetary differentiation</a> (for example, separation into layers such as a <a href="Planetary_core" title="Planetary core">core</a> and mantle); <a href="Outgassing" title="Outgassing">outgassing</a>; <a href="Fractional_crystallization_(geology)" title="Fractional crystallization (geology)">fractional crystallization</a>; and <a href="Partial_melting" title="Partial melting">partial melting</a>.<sup id="cite_ref-urPaper_1-4" class="reference"><a href="#cite_note-urPaper-1"><span class="cite-bracket">[</span>1<span class="cite-bracket">]</span></a></sup>
</p>
<div class="mw-heading mw-heading3"><h3 id="Intensive_variables_and_volatiles">Intensive variables and volatiles</h3></div>
<p>Allowable combinations of elements in minerals are determined by thermodynamics; for an element to be added to a crystal at a given location, it must reduce the energy. At higher temperatures, many elements are interchangeable in minerals such as <a href="Olivine" title="Olivine">olivine</a>.<sup id="cite_ref-Rosing_3-1" class="reference"><a href="#cite_note-Rosing-3"><span class="cite-bracket">[</span>3<span class="cite-bracket">]</span></a></sup> As a planet cools, minerals became exposed to a greater range of <a href="Intensive_and_extensive_properties" title="Intensive and extensive properties">intensive variables</a> such as temperature and pressure,<sup id="cite_ref-urPaper_1-5" class="reference"><a href="#cite_note-urPaper-1"><span class="cite-bracket">[</span>1<span class="cite-bracket">]</span></a></sup> allowing the formation of new phases and more specialized combinations of elements such as <a href="Clay_minerals" class="mw-redirect" title="Clay minerals">clay minerals</a> and <a href="Zeolite" title="Zeolite">zeolites</a>.<sup id="cite_ref-Rosing_3-2" class="reference"><a href="#cite_note-Rosing-3"><span class="cite-bracket">[</span>3<span class="cite-bracket">]</span></a></sup> New minerals are formed when volatile compounds such as <a href="Water" title="Water">water</a>, <a href="Carbon_dioxide" title="Carbon dioxide">carbon dioxide</a> and <a href="Oxygen" title="Oxygen">O<sub>2</sub></a> react with them. Environments such as <a href="Ice_cap" title="Ice cap">ice caps</a>, <a href="Dry_lake" title="Dry lake">dry lakes</a>, and exhumed <a href="Metamorphic_rock" title="Metamorphic rock">metamorphic rock</a> have distinctive suites of minerals.<sup id="cite_ref-urPaper_1-6" class="reference"><a href="#cite_note-urPaper-1"><span class="cite-bracket">[</span>1<span class="cite-bracket">]</span></a></sup>
</p>
<div class="mw-heading mw-heading3"><h3 id="Biological_influence">Biological influence</h3></div>
<p>Life has made dramatic changes in the environment. Most dramatic was the Great Oxygenation Event, about 2.4 billion years ago, in which <a href="Photosynthesis" title="Photosynthesis">photosynthetic</a> organisms flooded the atmosphere with oxygen. Living organisms also catalyze reactions, creating minerals such as <a href="Aragonite" title="Aragonite">aragonite</a> that are not in equilibrium with their surroundings.<sup id="cite_ref-urPaper_1-7" class="reference"><a href="#cite_note-urPaper-1"><span class="cite-bracket">[</span>1<span class="cite-bracket">]</span></a></sup><sup id="cite_ref-Fourth_12-0" class="reference"><a href="#cite_note-Fourth-12"><span class="cite-bracket">[</span>12<span class="cite-bracket">]</span></a></sup>
</p>
<div class="mw-heading mw-heading2"><h2 id="Chronology">Chronology</h2></div>
<p>Before the formation of the Solar System, there were about 12 minerals.<sup id="cite_ref-McCoy_5-3" class="reference"><a href="#cite_note-McCoy-5"><span class="cite-bracket">[</span>5<span class="cite-bracket">]</span></a></sup> The estimate for the current number of minerals has been changing rapidly. In 2008, it was 4300,<sup id="cite_ref-urPaper_1-8" class="reference"><a href="#cite_note-urPaper-1"><span class="cite-bracket">[</span>1<span class="cite-bracket">]</span></a></sup> but as of November 2018 there were 5413 officially recognized mineral species.<sup id="cite_ref-IMAMineralsCount_13-0" class="reference"><a href="#cite_note-IMAMineralsCount-13"><span class="cite-bracket">[</span>13<span class="cite-bracket">]</span></a></sup>
</p><p>In their chronology for Earth, Hazen et al. (2008) separated the changes in mineral abundance into three broad intervals: <a href="Planetary_accretion" class="mw-redirect" title="Planetary accretion">planetary accretion</a> up to 4.55 Ga (billion years ago); reworking of Earth's crust and mantle between 4.55 Ga and 2.5 Ga; and biological influences after 2.5 Ga.<sup id="cite_ref-urPaper_1-9" class="reference"><a href="#cite_note-urPaper-1"><span class="cite-bracket">[</span>1<span class="cite-bracket">]</span></a></sup><sup id="cite_ref-Fourth_12-1" class="reference"><a href="#cite_note-Fourth-12"><span class="cite-bracket">[</span>12<span class="cite-bracket">]</span></a></sup> They further divided the ages into 10 intervals, some of which overlap. In addition, some of the dates are uncertain; for example, estimates of the onset of modern plate tectonics range from 4.5 Ga to 1.0 Ga.<sup id="cite_ref-Bradley_14-0" class="reference"><a href="#cite_note-Bradley-14"><span class="cite-bracket">[</span>14<span class="cite-bracket">]</span></a></sup>
</p>
<table class="wikitable plainrowheaders">
<caption style="text-align: left;">Eras and stages of Earth's mineral evolution<sup id="cite_ref-Fourth_12-2" class="reference"><a href="#cite_note-Fourth-12"><span class="cite-bracket">[</span>12<span class="cite-bracket">]</span></a></sup>
</caption>
<tbody><tr>
<th scope="col" colspan="2">Era/stage
</th>
<th scope="col">Age (Ga)
</th>
<th scope="col">Cumulative no. of species
</th></tr>
<tr>
<th scope="row"><i>Prenebular "Ur-minerals"</i>
</th>
<td data-sort-value="" style="background: var(--background-color-interactive, #ececec); color: var(--color-base, inherit); vertical-align: middle; text-align: center;" class="table-na">—
</td>
<td>>4.6</td>
<td>12
</td></tr>
<tr>
<th scope="row" rowspan="2">Era of planetary accretion (>4.55 Ga)
</th>
<td>1. Sun ignites, heating nebula</td>
<td>>4.56</td>
<td>60
</td></tr>
<tr>
<td>2. Planetesimals form</td>
<td>>4.56–4.55</td>
<td>250
</td></tr>
<tr>
<th scope="row" rowspan="3">Era of crust and mantle reworking (4.55–2.5 Ga)
</th>
<td>3. Igneous rock evolution</td>
<td>4.55–4.0</td>
<td>350–420<sup id="cite_ref-15" class="reference"><a href="#cite_note-15"><span class="cite-bracket">[</span>a<span class="cite-bracket">]</span></a></sup>
</td></tr>
<tr>
<td>4. Granitoid and pegmatite formation</td>
<td>4.0–3.5</td>
<td>1000
</td></tr>
<tr>
<td>5. Plate tectonics</td>
<td>>3.0</td>
<td>1500
</td></tr>
<tr>
<th scope="row" rowspan="5">Era of biologically mediated mineralogy (2.5 Ga – present)
</th>
<td>6. Anoxic biological world</td>
<td>3.9–2.5</td>
<td>1500
</td></tr>
<tr>
<td>7. Great Oxidation Event</td>
<td>2.5–1.9</td>
<td>>4000
</td></tr>
<tr>
<td>8. Intermediate ocean</td>
<td>1.85–0.85<sup id="cite_ref-HazenBook_16-0" class="reference"><a href="#cite_note-HazenBook-16"><span class="cite-bracket">[</span>15<span class="cite-bracket">]</span></a></sup><sup class="reference nowrap"><span title="Page / location: 181">: 181 </span></sup></td>
<td>>4000
</td></tr>
<tr>
<td>9. Snowball Earth events</td>
<td>0.85–0.542</td>
<td>>4000
</td></tr>
<tr>
<td>10. Phanerozoic era of biomineralization</td>
<td><0.542</td>
<td>>5413<sup id="cite_ref-IMAMineralsCount_13-1" class="reference"><a href="#cite_note-IMAMineralsCount-13"><span class="cite-bracket">[</span>13<span class="cite-bracket">]</span></a></sup>
</td></tr></tbody></table>
<div class="mw-heading mw-heading3"><h3 id="Planetary_accretion">Planetary accretion</h3></div>
<div role="note" class="hatnote navigation-not-searchable">Main article: <a href="Planetary_accretion" class="mw-redirect" title="Planetary accretion">Planetary accretion</a></div>
<p>In the first era, the Sun ignited, heating the surrounding <a href="Molecular_cloud" title="Molecular cloud">molecular cloud</a>. 60 new minerals were produced and were preserved as inclusions in chondrites. The accretion of dust into asteroids and planets, bombardments, heating and reactions with water raised the number to 250.<sup id="cite_ref-Condie_8-1" class="reference"><a href="#cite_note-Condie-8"><span class="cite-bracket">[</span>8<span class="cite-bracket">]</span></a></sup><sup id="cite_ref-Fourth_12-3" class="reference"><a href="#cite_note-Fourth-12"><span class="cite-bracket">[</span>12<span class="cite-bracket">]</span></a></sup>
</p>
<div class="mw-heading mw-heading4"><h4 id="Stage_1:_Sun_ignites">Stage 1: Sun ignites</h4></div>
<p>Before 4.56 Ga, the <a href="Presolar_nebula" class="mw-redirect" title="Presolar nebula">presolar nebula</a> was a dense molecular cloud consisting of hydrogen and helium gas with dispersed dust grains. When the Sun ignited and entered its <a href="T_Tauri_star" title="T Tauri star">T-Tauri phase</a>, it melted nearby dust grains. Some of the melt droplets were incorporated into chondrites as small spherical objects called <a href="Chondrules" class="mw-redirect" title="Chondrules">chondrules</a>.<sup id="cite_ref-Fourth_12-4" class="reference"><a href="#cite_note-Fourth-12"><span class="cite-bracket">[</span>12<span class="cite-bracket">]</span></a></sup> Almost all chondrites also contain <a href="Calcium%E2%80%93aluminium-rich_inclusion" title="Calcium–aluminium-rich inclusion">calcium–aluminium-rich inclusions</a> (CAIs), the earliest materials formed in the Solar System.<sup id="cite_ref-McCoy_5-4" class="reference"><a href="#cite_note-McCoy-5"><span class="cite-bracket">[</span>5<span class="cite-bracket">]</span></a></sup> From an examination of chondrites from this era, 60 new minerals can be identified with crystal structures from all of the <a href="Crystal_system" title="Crystal system">crystal systems</a>.<sup id="cite_ref-McCoy_5-5" class="reference"><a href="#cite_note-McCoy-5"><span class="cite-bracket">[</span>5<span class="cite-bracket">]</span></a></sup> These included the first <a href="Iron-nickel_alloy" class="mw-redirect" title="Iron-nickel alloy">iron-nickel alloys</a>, <a href="Sulfide_minerals" class="mw-redirect" title="Sulfide minerals">sulfides</a>, <a href="Phosphide" title="Phosphide">phosphides</a>, and several silicates and <a href="Oxide_minerals" class="mw-redirect" title="Oxide minerals">oxides</a>.<sup id="cite_ref-Fourth_12-5" class="reference"><a href="#cite_note-Fourth-12"><span class="cite-bracket">[</span>12<span class="cite-bracket">]</span></a></sup> Among the most important were magnesium-rich olivine, magnesium-rich <a href="Pyroxene" title="Pyroxene">pyroxene</a>, and <a href="Plagioclase" title="Plagioclase">plagioclase</a>. Some rare minerals, produced in oxygen-poor environments no longer found on Earth, can be found in enstatite chondrites.<sup id="cite_ref-McCoy_5-6" class="reference"><a href="#cite_note-McCoy-5"><span class="cite-bracket">[</span>5<span class="cite-bracket">]</span></a></sup>
</p>
<div class="mw-heading mw-heading4"><h4 id="Stage_2:_Planetesimals_form">Stage 2: Planetesimals form</h4></div>
<p>Soon after the new minerals formed in Stage 1, they began to clump together, forming <a href="Asteroid" title="Asteroid">asteroids</a> and planets. One of the most important new minerals was <a href="Ice" title="Ice">ice</a>; the early Solar System had a "snow line" separating rocky planets and asteroids from ice-rich <a href="Giant_planet" title="Giant planet">giant planets</a>, <a href="Trans-Neptunian_object" title="Trans-Neptunian object">trans-Neptunian objects</a>, and <a href="Comet" title="Comet">comets</a>. Heating from <a href="Radionuclide" title="Radionuclide">radionuclides</a> melted the ice and the water reacted with olivine-rich rocks, forming <a href="Phyllosilicate" class="mw-redirect" title="Phyllosilicate">phyllosilicates</a>, oxides such as <a href="Magnetite" title="Magnetite">magnetite</a>, sulfides such as <a href="Pyrrhotite" title="Pyrrhotite">pyrrhotite</a>, the <a href="Carbonate" title="Carbonate">carbonates</a> <a href="Dolomite_(mineral)" title="Dolomite (mineral)">dolomite</a> and <a href="Calcite" title="Calcite">calcite</a>, and <a href="Sulfate" title="Sulfate">sulfates</a> such as <a href="Gypsum" title="Gypsum">gypsum</a>. Shock and heat from bombardment and eventual melting produced minerals such as <a href="Ringwoodite" title="Ringwoodite">ringwoodite</a>, a major component of Earth's mantle.<sup id="cite_ref-McCoy_5-7" class="reference"><a href="#cite_note-McCoy-5"><span class="cite-bracket">[</span>5<span class="cite-bracket">]</span></a></sup>
</p><p>Eventually, asteroids heated enough for partial melting to occur, producing melts rich in pyroxene and plagioclase (capable of producing <a href="Basalt" title="Basalt">basalt</a>) and a variety of <a href="Phosphate" title="Phosphate">phosphates</a>. <a href="Siderophile_element" class="mw-redirect" title="Siderophile element">Siderophile</a> (metal-loving) and <a href="Lithophile" title="Lithophile">lithophile</a> (silicate-loving) elements separated, leading to the formation of a core and crust, and <a href="Incompatible_element" title="Incompatible element">incompatible elements</a> were sequestered in the melts.<sup id="cite_ref-McCoy_5-8" class="reference"><a href="#cite_note-McCoy-5"><span class="cite-bracket">[</span>5<span class="cite-bracket">]</span></a></sup> The resulting minerals have been preserved in a type of stony meteorite, <a href="Eucrite" title="Eucrite">eucrite</a> (<a href="Quartz" title="Quartz">quartz</a>, potassium <a href="Feldspar" title="Feldspar">feldspar</a>, <a href="Titanite" title="Titanite">titanite</a> and <a href="Zircon" title="Zircon">zircon</a>) and in <a href="Iron_meteorite" title="Iron meteorite">iron-nickel meteorites</a> (iron-nickel alloys such as <a href="Kamacite" title="Kamacite">kamacite</a> and <a href="Taenite" title="Taenite">taenite</a>; <a href="Transition_metal" title="Transition metal">transition metal</a> sulfides such as <a href="Troilite" title="Troilite">troilite</a>; <a href="Native_element_minerals" class="mw-redirect" title="Native element minerals">carbides and phosphides</a>).<sup id="cite_ref-urPaper_1-10" class="reference"><a href="#cite_note-urPaper-1"><span class="cite-bracket">[</span>1<span class="cite-bracket">]</span></a></sup> An estimated 250 new minerals formed in this stage.<sup id="cite_ref-Condie_8-2" class="reference"><a href="#cite_note-Condie-8"><span class="cite-bracket">[</span>8<span class="cite-bracket">]</span></a></sup><sup id="cite_ref-Fourth_12-6" class="reference"><a href="#cite_note-Fourth-12"><span class="cite-bracket">[</span>12<span class="cite-bracket">]</span></a></sup>
</p>
<div class="mw-heading mw-heading3"><h3 id="Crust_and_mantle_reworking">Crust and mantle reworking</h3></div>
<p>The second era in the history of mineral evolution began with the massive impact that formed the Moon. This melted most of the crust and mantle. Early mineralogy was determined by crystallization of igneous rocks and further bombardments. This phase was then replaced by extensive recycling of crust and mantle, so that at the end of this era there were about 1500 mineral species. However, few of the rocks survived from this period so the timing of many events remains uncertain.<sup id="cite_ref-urPaper_1-11" class="reference"><a href="#cite_note-urPaper-1"><span class="cite-bracket">[</span>1<span class="cite-bracket">]</span></a></sup>
</p>
<div class="mw-heading mw-heading4"><h4 id="Stage_3:_Igneous_processes">Stage 3: Igneous processes</h4></div>
<p>Stage 3 began with a crust made of <a href="Mafic" title="Mafic">mafic</a> (high in iron and magnesium) and <a href="Ultramafic" class="mw-redirect" title="Ultramafic">ultramafic</a> rocks such as basalt. These rocks were repeatedly recycled by fractional melting, fractional crystallization and separation of <a href="Magma" title="Magma">magmas</a> that refuse to mix. An example of such a process is <a href="Bowen's_reaction_series" title="Bowen's reaction series">Bowen's reaction series</a>.<sup id="cite_ref-urPaper_1-12" class="reference"><a href="#cite_note-urPaper-1"><span class="cite-bracket">[</span>1<span class="cite-bracket">]</span></a></sup>
</p><p>One of the few sources of direct information on mineralogy in this stage is mineral inclusions in zircon crystals, which date as far back as 4.4 Ga. Among the minerals in the inclusions are quartz, <a href="Muscovite" title="Muscovite">muscovite</a>, <a href="Biotite" title="Biotite">biotite</a>, <a href="Potassium_feldspar" title="Potassium feldspar">potassium feldspar</a>, <a href="Albite" title="Albite">albite</a>, <a href="Chlorite" title="Chlorite">chlorite</a> and <a href="Hornblende" title="Hornblende">hornblende</a>.<sup id="cite_ref-Papineau_17-0" class="reference"><a href="#cite_note-Papineau-17"><span class="cite-bracket">[</span>16<span class="cite-bracket">]</span></a></sup>
</p><p>In a volatile-poor body such as <a href="Mercury_(planet)" title="Mercury (planet)">Mercury</a> and the Moon, the above processes give rise to about 350 mineral species. Water and other volatiles, if present, increase the total. Earth was volatile-rich, with an atmosphere composed of N<sub>2</sub>, CO<sub>2</sub> and water, and an ocean that became steadily more saline. <a href="Volcanism" title="Volcanism">Volcanism</a>, outgassing and <a href="Mineral_hydration" title="Mineral hydration">hydration</a> gave rise to <a href="Hydroxide_minerals" class="mw-redirect" title="Hydroxide minerals">hydroxides</a>, <a href="Hydrate" title="Hydrate">hydrates</a>, <a href="Carbonate_minerals" class="mw-redirect" title="Carbonate minerals">carbonates</a> and <a href="Evaporite" title="Evaporite">evaporites</a>. For Earth, where this stage coincides with the <a href="Hadean" title="Hadean">Hadean</a> Eon, the total number of widely occurring minerals is estimated to be 420, with over 100 more that were rare.<sup id="cite_ref-Hadean_6-2" class="reference"><a href="#cite_note-Hadean-6"><span class="cite-bracket">[</span>6<span class="cite-bracket">]</span></a></sup> <a href="Mars" title="Mars">Mars</a> probably reached this stage of mineral evolution.<sup id="cite_ref-urPaper_1-13" class="reference"><a href="#cite_note-urPaper-1"><span class="cite-bracket">[</span>1<span class="cite-bracket">]</span></a></sup>
</p>
<div class="mw-heading mw-heading4"><h4 id="Stage_4:_Granitoids_and_pegmatite_formation">Stage 4: Granitoids and pegmatite formation</h4></div>
<p>Given sufficient heat, basalt was remelted to form <a href="Granitoid" title="Granitoid">granitoids</a>, coarse-grained rocks similar to granite. Cycles of melting concentrated rare elements such as lithium, <a href="Beryllium" title="Beryllium">beryllium</a>, boron, <a href="Niobium" title="Niobium">niobium</a>, <a href="Tantalum" title="Tantalum">tantalum</a> and <a href="Uranium" title="Uranium">uranium</a> to the point where they could form 500 new minerals. Many of these are concentrated in exceptionally coarse-grained rocks called <a href="Pegmatite" title="Pegmatite">pegmatites</a> that are typically found in <a href="Dike_(geology)" title="Dike (geology)">dikes</a> and <a href="Vein_(geology)" title="Vein (geology)">veins</a> near larger igneous masses. Venus may have achieved this level of evolution.<sup id="cite_ref-Fourth_12-7" class="reference"><a href="#cite_note-Fourth-12"><span class="cite-bracket">[</span>12<span class="cite-bracket">]</span></a></sup>
</p>
<div class="mw-heading mw-heading4"><h4 id="Stage_5:_Plate_tectonics">Stage 5: Plate tectonics</h4></div>
<p>With the onset of plate tectonics, <a href="Subduction" title="Subduction">subduction</a> carried crust and water down, leading to fluid-rock interactions and more concentration of rare elements. In particular, sulfide deposits were formed with 150 new <a href="Sulfosalt_minerals" class="mw-redirect" title="Sulfosalt minerals">sulfosalt minerals</a>. Subduction also carried cooler rock into the mantle and exposed it to higher pressures, resulting in new phases that were later uplifted and exposed as <a href="Metamorphic_mineral" class="mw-redirect" title="Metamorphic mineral">metamorphic minerals</a> such as <a href="Kyanite" title="Kyanite">kyanite</a> and <a href="Sillimanite" title="Sillimanite">sillimanite</a>.<sup id="cite_ref-Fourth_12-8" class="reference"><a href="#cite_note-Fourth-12"><span class="cite-bracket">[</span>12<span class="cite-bracket">]</span></a></sup>
</p>
<div class="mw-heading mw-heading3"><h3 id="Biologically_mediated_mineralogy">Biologically mediated mineralogy</h3></div>
<p>The inorganic processes described in the previous section produced about 1500 mineral species. The remaining more than two-thirds of Earth's minerals are the result of the transformation of Earth by living organisms.<sup id="cite_ref-Fourth_12-9" class="reference"><a href="#cite_note-Fourth-12"><span class="cite-bracket">[</span>12<span class="cite-bracket">]</span></a></sup> The largest contribution was from the enormous increase in the oxygen content of the atmosphere, starting with the Great Oxygenation Event.<sup id="cite_ref-Gross_18-0" class="reference"><a href="#cite_note-Gross-18"><span class="cite-bracket">[</span>17<span class="cite-bracket">]</span></a></sup> Living organisms also started to produce <a href="Skeleton" title="Skeleton">skeletons</a> and other forms of <a href="Biomineralization" title="Biomineralization">biomineralization</a>.<sup id="cite_ref-Dove_19-0" class="reference"><a href="#cite_note-Dove-19"><span class="cite-bracket">[</span>18<span class="cite-bracket">]</span></a></sup> Minerals such as calcite, metal oxides and many clay minerals could be considered <a href="Biosignatures" class="mw-redirect" title="Biosignatures">biosignatures</a>,<sup id="cite_ref-Yeager_20-0" class="reference"><a href="#cite_note-Yeager-20"><span class="cite-bracket">[</span>19<span class="cite-bracket">]</span></a></sup> along with gems such as <a href="Turquoise" title="Turquoise">turquoise</a>, <a href="Azurite" title="Azurite">azurite</a> and <a href="Malachite" title="Malachite">malachite</a>.<sup id="cite_ref-HazenBook_16-1" class="reference"><a href="#cite_note-HazenBook-16"><span class="cite-bracket">[</span>15<span class="cite-bracket">]</span></a></sup><sup class="reference nowrap"><span title="Page / location: 177">: 177 </span></sup>
</p>
<div class="mw-heading mw-heading4"><h4 id="Stage_6:_Biology_in_an_anoxic_world">Stage 6: Biology in an anoxic world</h4></div>
<p>Before about 2.45 Ga, there was very little oxygen in the atmosphere. Life may have played a role in the precipitation of massive carbonate layers near continental margins and in the deposition of banded iron formations,<sup id="cite_ref-urPaper_1-14" class="reference"><a href="#cite_note-urPaper-1"><span class="cite-bracket">[</span>1<span class="cite-bracket">]</span></a></sup> but there is no unambiguous evidence of the effect of life on minerals.<sup id="cite_ref-Papineau_17-1" class="reference"><a href="#cite_note-Papineau-17"><span class="cite-bracket">[</span>16<span class="cite-bracket">]</span></a></sup>
</p>
<div class="mw-heading mw-heading4"><h4 id="Stage_7:_Great_Oxygenation_Event">Stage 7: Great Oxygenation Event</h4></div>
<p>Starting around 2.45 Ga and continuing to about 2.0 or 1.9 Ga, there was a dramatic rise in the oxygen content of the lower atmosphere, continents and oceans called the Great Oxygenation Event or Great Oxidation Event (GOE). Before the GOE, elements that can be in multiple oxidation states were restricted to the lowest state, and that limited the variety of minerals they could form. In older sediments, the minerals <a href="Siderite" title="Siderite">siderite</a> (FeCO<sub>3</sub>), <a href="Uraninite" title="Uraninite">uraninite</a> (UO<sub>2</sub>) and <a href="Pyrite" title="Pyrite">pyrite</a> (FeS<sub>2</sub>) are commonly found. These oxidize rapidly when exposed to an atmosphere with oxygen, yet this did not occur even after extensive weathering and transport.<sup id="cite_ref-Sverjensky_21-0" class="reference"><a href="#cite_note-Sverjensky-21"><span class="cite-bracket">[</span>20<span class="cite-bracket">]</span></a></sup>
</p><p>When the concentration of oxygen molecules in the atmosphere reached 1% of the present level, the chemical reactions during weathering were much like they are today. Siderite and pyrite were replaced by the iron oxides magnetite and <a href="Hematite" title="Hematite">hematite</a>; dissolved Fe<sup>2+</sup> ions that had been carried out to sea were now deposited in extensive banded iron formations. However, this did not result in new iron minerals, just a change in their abundance. By contrast, oxidization of uraninite resulted in over 200 new species of <a href="Uranyl" title="Uranyl">uranyl</a> minerals such as <a href="Soddyite" title="Soddyite">soddyite</a> and <a href="Weeksite" title="Weeksite">weeksite</a>, as well as mineral complexes such as <a href="Gummite" title="Gummite">gummite</a>.<sup id="cite_ref-Sverjensky_21-1" class="reference"><a href="#cite_note-Sverjensky-21"><span class="cite-bracket">[</span>20<span class="cite-bracket">]</span></a></sup>
</p><p>Other elements that have multiple oxidation states include <a href="Copper" title="Copper">copper</a> (which occurs in 321 oxides and silicates), boron, <a href="Vanadium" title="Vanadium">vanadium</a>, <a href="Magnesium" title="Magnesium">magnesium</a>, <a href="Selenium" title="Selenium">selenium</a>, <a href="Tellurium" title="Tellurium">tellurium</a>, <a href="Arsenic" title="Arsenic">arsenic</a>, <a href="Antimony" title="Antimony">antimony</a>, <a href="Bismuth" title="Bismuth">bismuth</a>, <a href="Silver" title="Silver">silver</a> and <a href="Mercury_(element)" title="Mercury (element)">mercury</a>.<sup id="cite_ref-Sverjensky_21-2" class="reference"><a href="#cite_note-Sverjensky-21"><span class="cite-bracket">[</span>20<span class="cite-bracket">]</span></a></sup> In total, about 2500 new minerals formed.<sup id="cite_ref-Fourth_12-10" class="reference"><a href="#cite_note-Fourth-12"><span class="cite-bracket">[</span>12<span class="cite-bracket">]</span></a></sup>
</p>
<div class="mw-heading mw-heading4"><h4 id="Stage_8:_Intermediate_ocean">Stage 8: Intermediate ocean</h4></div>
<p>The next roughly billion years (1.85–0.85 Ga) are often referred to as the "<a href="Boring_Billion" title="Boring Billion">Boring Billion</a>" because little seemed to happen. The more oxidized layer of ocean water near the surface slowly deepened at the expense of the <a href="Anoxic_waters" title="Anoxic waters">anoxic</a> depths, but there did not seem to be any dramatic change in climate, biology or mineralogy. However, some of this perception may be due to poor preservation of rocks from that time span. Many of the world's most valuable reserves of lead, zinc and silver, are found in rocks from this time, as well as rich sources of beryllium, boron and uranium minerals.<sup id="cite_ref-HazenBook_16-2" class="reference"><a href="#cite_note-HazenBook-16"><span class="cite-bracket">[</span>15<span class="cite-bracket">]</span></a></sup><sup class="reference nowrap"><span title="Page / location: 181">: 181 </span></sup> This interval also saw the formation of the <a href="Supercontinent" title="Supercontinent">supercontinent</a> <a href="Columbia_(supercontinent)" title="Columbia (supercontinent)">Columbia</a>, its breakup, and the formation of <a href="Rodinia" title="Rodinia">Rodinia</a>.<sup id="cite_ref-HazenBook_16-3" class="reference"><a href="#cite_note-HazenBook-16"><span class="cite-bracket">[</span>15<span class="cite-bracket">]</span></a></sup><sup class="reference nowrap"><span title="Page / location: 195">: 195 </span></sup> In some quantitative studies of beryllium, boron and mercury minerals, there are no new minerals during the Great Oxidation Event, but a pulse of innovation during the assembly of Columbia. The reasons for this are not clear, although it may have had something to do with the release of mineralizing fluids during <a href="Orogeny" title="Orogeny">mountain building</a>.<sup id="cite_ref-HazenBook_16-4" class="reference"><a href="#cite_note-HazenBook-16"><span class="cite-bracket">[</span>15<span class="cite-bracket">]</span></a></sup><sup class="reference nowrap"><span title="Page / location: 202–204">: 202–204 </span></sup>
</p>
<div class="mw-heading mw-heading4"><h4 id="Stage_9:_Snowball_Earth">Stage 9: Snowball Earth</h4></div>
<p>Between 1.0 and 0.542 Ga, the Earth experienced at least two "<a href="Snowball_Earth" title="Snowball Earth">Snowball Earth</a>" events in which much (possibly all) of the surface was covered by ice (making it the dominant surface mineral). Associated with the ice were <a href="Cap_carbonate" title="Cap carbonate">cap carbonates</a>, thick layers of <a href="Limestone" title="Limestone">limestone</a> or <a href="Dolomite_(rock)" title="Dolomite (rock)">dolomite</a>, with aragonite fans.<sup id="cite_ref-22" class="reference"><a href="#cite_note-22"><span class="cite-bracket">[</span>21<span class="cite-bracket">]</span></a></sup> Clay minerals were also produced in abundance, and volcanoes managed to pierce through the ice and add to the stock of minerals.<sup id="cite_ref-Fourth_12-11" class="reference"><a href="#cite_note-Fourth-12"><span class="cite-bracket">[</span>12<span class="cite-bracket">]</span></a></sup>
</p>
<div class="mw-heading mw-heading4"><h4 id="Stage_10:_Phanerozoic_era_and_biomineralization">Stage 10: Phanerozoic era and biomineralization</h4></div>
<p>The last stage coincides with the <a href="Phanerozoic_era" class="mw-redirect" title="Phanerozoic era">Phanerozoic era</a>, in which biomineralization, the creation of minerals by living organisms, became widespread.<sup id="cite_ref-Fourth_12-12" class="reference"><a href="#cite_note-Fourth-12"><span class="cite-bracket">[</span>12<span class="cite-bracket">]</span></a></sup> Although some biominerals can be found in earlier records, it was during the <a href="Cambrian_explosion" title="Cambrian explosion">Cambrian explosion</a> that most of the known skeletal forms developed,<sup id="cite_ref-Dove_19-1" class="reference"><a href="#cite_note-Dove-19"><span class="cite-bracket">[</span>18<span class="cite-bracket">]</span></a></sup> and the major skeletal minerals (calcite, aragonite, <a href="Apatite" title="Apatite">apatite</a> and <a href="Opal" title="Opal">opal</a>).<sup id="cite_ref-urPaper_1-15" class="reference"><a href="#cite_note-urPaper-1"><span class="cite-bracket">[</span>1<span class="cite-bracket">]</span></a></sup> Most of these are carbonates, but some are phosphates or calcite. In all, over 64 mineral phases have been identified in living organisms, including metal sulfides, oxides, hydroxides and silicates;<sup id="cite_ref-Dove_19-2" class="reference"><a href="#cite_note-Dove-19"><span class="cite-bracket">[</span>18<span class="cite-bracket">]</span></a></sup> over two dozen have been found in the human body.<sup id="cite_ref-urPaper_1-16" class="reference"><a href="#cite_note-urPaper-1"><span class="cite-bracket">[</span>1<span class="cite-bracket">]</span></a></sup>
</p><p>Before the Phanerozoic, land was mostly barren rock, but plants began to populate it in the <a href="Silurian" title="Silurian">Silurian Period</a>. This led to an order-of-magnitude increase in the production of clay minerals. In the oceans, <a href="Plankton" title="Plankton">plankton</a> transported <a href="Calcium_carbonate" title="Calcium carbonate">calcium carbonate</a> from shallow waters to the deep ocean, inhibiting the production of cap carbonates and making future snowball Earth events less likely. Microbes also became involved in the <a href="Geochemical_cycle" title="Geochemical cycle">geochemical cycles</a> of most elements, making them <a href="Biogeochemical_cycle" title="Biogeochemical cycle">biogeochemical cycles</a>. The mineralogical novelties included <a href="Organic_mineral" title="Organic mineral">organic minerals</a> that have been found in carbon-rich remnants of life such as <a href="Coal" title="Coal">coal</a> and black <a href="Shale" title="Shale">shales</a>.<sup id="cite_ref-urPaper_1-17" class="reference"><a href="#cite_note-urPaper-1"><span class="cite-bracket">[</span>1<span class="cite-bracket">]</span></a></sup>
</p>
<div class="mw-heading mw-heading3"><h3 id="Anthropocene">Anthropocene</h3></div>
<p>Strictly speaking, purely biogenic minerals are not recognized by the <a href="International_Mineralogical_Association" title="International Mineralogical Association">International Mineralogical Association</a> (IMA) unless geological processes are also involved. Purely biological products such as the shells of marine organisms are not accepted. Also explicitly excluded are <a href="Human_impact_on_the_environment" title="Human impact on the environment">anthropogenic</a> compounds.<sup id="cite_ref-Nickel_24-0" class="reference"><a href="#cite_note-Nickel-24"><span class="cite-bracket">[</span>23<span class="cite-bracket">]</span></a></sup> However, humans have had such an impact on the surface of the planet that geologists are considering the introduction of a new <a href="Epoch_(geology)" class="mw-redirect" title="Epoch (geology)">geological epoch</a>, the <a href="Anthropocene" title="Anthropocene">Anthropocene</a>, to reflect these changes.<sup id="cite_ref-25" class="reference"><a href="#cite_note-25"><span class="cite-bracket">[</span>24<span class="cite-bracket">]</span></a></sup><sup id="cite_ref-Heaney_26-0" class="reference"><a href="#cite_note-Heaney-26"><span class="cite-bracket">[</span>25<span class="cite-bracket">]</span></a></sup>
</p><p>In 2015, Zalasiewicz and co-authors proposed that the definition of minerals be extended to include human-minerals and that their production constitutes an 11th stage of mineral evolution.<sup id="cite_ref-Gross_18-1" class="reference"><a href="#cite_note-Gross-18"><span class="cite-bracket">[</span>17<span class="cite-bracket">]</span></a></sup><sup id="cite_ref-27" class="reference"><a href="#cite_note-27"><span class="cite-bracket">[</span>26<span class="cite-bracket">]</span></a></sup> Subsequently, Hazen and co-authors catalogued 208 minerals that are officially recognized by the IMA but are primarily or exclusively the result of human activities. Most of these have formed in association with <a href="Mining" title="Mining">mining</a>. In addition, some were created when metal artefacts sank and interacted with the seafloor. A few would probably not be officially recognized today but are allowed to remain in the catalog; these include two (<a href="Niobium_carbide" title="Niobium carbide">niobocarbide</a> and <a href="Tantalcarbide" title="Tantalcarbide">tantalcarbide</a>) that may have been a hoax.<sup id="cite_ref-Heaney_26-1" class="reference"><a href="#cite_note-Heaney-26"><span class="cite-bracket">[</span>25<span class="cite-bracket">]</span></a></sup><sup id="cite_ref-Anthropocene_28-0" class="reference"><a href="#cite_note-Anthropocene-28"><span class="cite-bracket">[</span>27<span class="cite-bracket">]</span></a></sup><sup id="cite_ref-DCO208_29-0" class="reference"><a href="#cite_note-DCO208-29"><span class="cite-bracket">[</span>28<span class="cite-bracket">]</span></a></sup><sup id="cite_ref-Shannon_30-0" class="reference"><a href="#cite_note-Shannon-30"><span class="cite-bracket">[</span>29<span class="cite-bracket">]</span></a></sup>
</p><p>Hazen and co-authors identified three ways that humans have had a large impact on the distribution and diversity of minerals. The first is through manufacture. A long list of synthetic crystals have mineral equivalents, including synthetic gems, ceramics, brick, cement and batteries.<sup id="cite_ref-Shannon_30-1" class="reference"><a href="#cite_note-Shannon-30"><span class="cite-bracket">[</span>29<span class="cite-bracket">]</span></a></sup> Many more have no mineral equivalent; over 180,000 inorganic crystalline compounds are listed in the <a href="Inorganic_Crystal_Structure_Database" title="Inorganic Crystal Structure Database">Inorganic Crystal Structure Database</a>.<sup id="cite_ref-Anthropocene_28-1" class="reference"><a href="#cite_note-Anthropocene-28"><span class="cite-bracket">[</span>27<span class="cite-bracket">]</span></a></sup> For mining or building of infrastructure, humans have redistributed rocks, sediments and minerals on a scale rivalling that of glaciation, and valuable minerals have been redistributed and juxtaposed in ways that would not occur naturally.<sup id="cite_ref-DCO208_29-1" class="reference"><a href="#cite_note-DCO208-29"><span class="cite-bracket">[</span>28<span class="cite-bracket">]</span></a></sup>
</p>
<div class="mw-heading mw-heading2"><h2 id="Origin_of_life">Origin of life</h2></div>
<p>Over two-thirds of mineral species owe their existence to life,<sup id="cite_ref-Fourth_12-13" class="reference"><a href="#cite_note-Fourth-12"><span class="cite-bracket">[</span>12<span class="cite-bracket">]</span></a></sup> but life may also owe its existence to minerals. They may have been needed as templates to bring organic molecules together; as <a href="Catalyst" class="mw-redirect" title="Catalyst">catalysts</a> for chemical reactions; and as <a href="Metabolite" title="Metabolite">metabolites</a>.<sup id="cite_ref-urPaper_1-18" class="reference"><a href="#cite_note-urPaper-1"><span class="cite-bracket">[</span>1<span class="cite-bracket">]</span></a></sup> Two prominent theories for the origin of life involve clays and transition metal sulfides.<sup id="cite_ref-Dawkins_31-0" class="reference"><a href="#cite_note-Dawkins-31"><span class="cite-bracket">[</span>30<span class="cite-bracket">]</span></a></sup><sup id="cite_ref-32" class="reference"><a href="#cite_note-32"><span class="cite-bracket">[</span>31<span class="cite-bracket">]</span></a></sup> Another theory argues that calcium-borate minerals such as <a href="Colemanite" title="Colemanite">colemanite</a> and <a href="Borate" title="Borate">borate</a>, and possibly also <a href="Molybdate" title="Molybdate">molybdate</a>, may have been needed for the first <a href="Ribonucleic_acid" class="mw-redirect" title="Ribonucleic acid">ribonucleic acid</a> (RNA) to form.<sup id="cite_ref-33" class="reference"><a href="#cite_note-33"><span class="cite-bracket">[</span>32<span class="cite-bracket">]</span></a></sup><sup id="cite_ref-34" class="reference"><a href="#cite_note-34"><span class="cite-bracket">[</span>33<span class="cite-bracket">]</span></a></sup> Other theories require less common minerals such as <a href="Mackinawite" title="Mackinawite">mackinawite</a> or <a href="Greigite" title="Greigite">greigite</a>.<sup id="cite_ref-urPaper_1-19" class="reference"><a href="#cite_note-urPaper-1"><span class="cite-bracket">[</span>1<span class="cite-bracket">]</span></a></sup> A catalog of the minerals that were formed during the Hadean Eon includes clay minerals and iron and nickel sulfides, including mackinawite and greigite; but borates and molybdates were unlikely.<sup id="cite_ref-Hadean_6-3" class="reference"><a href="#cite_note-Hadean-6"><span class="cite-bracket">[</span>6<span class="cite-bracket">]</span></a></sup><sup id="cite_ref-35" class="reference"><a href="#cite_note-35"><span class="cite-bracket">[</span>34<span class="cite-bracket">]</span></a></sup><sup id="cite_ref-36" class="reference"><a href="#cite_note-36"><span class="cite-bracket">[</span>35<span class="cite-bracket">]</span></a></sup>
</p><p>Minerals may also have been necessary to the survival of early life. For example, quartz is more transparent than other minerals in <a href="Sandstone" title="Sandstone">sandstones</a>. Before life developed <a href="Pigment" title="Pigment">pigments</a> to protect it from damaging <a href="Ultraviolet_ray" class="mw-redirect" title="Ultraviolet ray">ultraviolet rays</a>, a thin layer of quartz could shield it while allowing enough light through for photosynthesis. Phosphate minerals may also have been important to early life. Phosphorus is one of the essential elements in molecules such as <a href="Adenosine_triphosphate" title="Adenosine triphosphate">adenosine triphosphate</a> (ATP), an energy carrier found in all living cells; RNA and <a href="DNA" title="DNA">DNA</a>; and <a href="Cell_membrane" title="Cell membrane">cell membranes</a>. Most of Earth's phosphorus is in the core and mantle. The most likely mechanism for making it available to life would be the creation of phosphates such as apatite through fractionation, followed by weathering to release the phosphorus. This may have required plate tectonics.<sup id="cite_ref-37" class="reference"><a href="#cite_note-37"><span class="cite-bracket">[</span>36<span class="cite-bracket">]</span></a></sup><sup id="cite_ref-38" class="reference"><a href="#cite_note-38"><span class="cite-bracket">[</span>37<span class="cite-bracket">]</span></a></sup>
</p>
<div class="mw-heading mw-heading2"><h2 id="Further_research">Further research</h2></div>
<p>Since the original paper on mineral evolution, there have been several studies of minerals of specific elements, including uranium, <a href="Thorium" title="Thorium">thorium</a>, mercury, carbon, beryllium, and the clay minerals. These reveal information about different processes; for example, uranium and thorium are heat producers while uranium and carbon indicate oxidation state.<sup id="cite_ref-Bradley_14-1" class="reference"><a href="#cite_note-Bradley-14"><span class="cite-bracket">[</span>14<span class="cite-bracket">]</span></a></sup> The records reveal episodic bursts of new minerals such as those during the <a href="#Intermediate_ocean">Boring Billion</a>, as well as long periods where no new minerals appeared. For example, after a jump in diversity during the assembly of Columbia, there were no new mercury minerals between 1.8 Ga and 600 million years ago. This remarkably long hiatus is attributed to a sulfide-rich ocean, which led to rapid deposition of the mineral <a href="Cinnabar" title="Cinnabar">cinnabar</a>.<sup id="cite_ref-HazenBook_16-5" class="reference"><a href="#cite_note-HazenBook-16"><span class="cite-bracket">[</span>15<span class="cite-bracket">]</span></a></sup><sup class="reference nowrap"><span title="Page / location: 204">: 204 </span></sup>
</p><p>Most of the mineral evolution papers have looked at the first appearance of minerals, but one can also look at the age distribution of a given mineral. Millions of zircon crystals have been dated, and the age distributions are nearly independent of where the crystals are found (e.g., igneous rocks, <a href="Sedimentary_rock" title="Sedimentary rock">sedimentary</a> or <a href="Metasedimentary_rock" title="Metasedimentary rock">metasedimentary rocks</a> or modern river sands). They have highs and lows that are linked with the supercontinent cycle, although it is not clear whether this is due to changes in subduction activity or preservation.<sup id="cite_ref-Bradley_14-2" class="reference"><a href="#cite_note-Bradley-14"><span class="cite-bracket">[</span>14<span class="cite-bracket">]</span></a></sup>
</p><p>Other studies have looked at time variations of mineral properties such as isotope ratios, chemical compositions, and relative abundances of minerals, although not under the rubric of "mineral evolution".<sup id="cite_ref-Needs_39-0" class="reference"><a href="#cite_note-Needs-39"><span class="cite-bracket">[</span>38<span class="cite-bracket">]</span></a></sup>
</p>
<div class="mw-heading mw-heading2"><h2 id="History">History</h2></div>
<p>For most of its history, mineralogy had no historical component. It was concerned with classifying minerals according to their chemical and physical properties (such as the chemical formula and crystal structure) and defining conditions for stability of a mineral or group of minerals.<sup id="cite_ref-urPaper_1-20" class="reference"><a href="#cite_note-urPaper-1"><span class="cite-bracket">[</span>1<span class="cite-bracket">]</span></a></sup> However, there were exceptions where publications looked at the distribution of ages of minerals or of ores. In 1960, Russell Gordon Gastil found cycles in the distribution of mineral dates.<sup id="cite_ref-40" class="reference"><a href="#cite_note-40"><span class="cite-bracket">[</span>39<span class="cite-bracket">]</span></a></sup> Charles Meyer, finding that the ores of some elements are distributed over a wider time span than others, attributed the difference to the effects of tectonics and biomass on the surface chemistry, particularly free oxygen and carbon.<sup id="cite_ref-41" class="reference"><a href="#cite_note-41"><span class="cite-bracket">[</span>40<span class="cite-bracket">]</span></a></sup> In 1979, A. G. Zhabin introduced the concept of stages of mineral evolution in the Russian-language journal <a href="Doklady_Akademii_Nauk" class="mw-redirect" title="Doklady Akademii Nauk">Doklady Akademii Nauk</a> and in 1982, N. P. Yushkin noted the increasing complexity of minerals over time near the surface of the Earth.<sup id="cite_ref-42" class="reference"><a href="#cite_note-42"><span class="cite-bracket">[</span>41<span class="cite-bracket">]</span></a></sup><sup id="cite_ref-Krivovichev_43-0" class="reference"><a href="#cite_note-Krivovichev-43"><span class="cite-bracket">[</span>42<span class="cite-bracket">]</span></a></sup> Then, in 2008, Hazen and colleagues introduced a much broader and more detailed vision of mineral evolution. This was followed by a series of quantitative explorations of the evolution of various mineral groups. These led in 2015 to the concept of <a href="Mineral_ecology" class="mw-redirect" title="Mineral ecology">mineral ecology</a>, the study of distributions of minerals in space and time.<sup id="cite_ref-Krivovichev_43-1" class="reference"><a href="#cite_note-Krivovichev-43"><span class="cite-bracket">[</span>42<span class="cite-bracket">]</span></a></sup><sup id="cite_ref-44" class="reference"><a href="#cite_note-44"><span class="cite-bracket">[</span>43<span class="cite-bracket">]</span></a></sup>
</p><p>In April 2017, the <a href="Natural_History_Museum%2C_Vienna" title="Natural History Museum, Vienna">Natural History Museum in Vienna</a> opened a new permanent exhibit on mineral evolution.<sup id="cite_ref-45" class="reference"><a href="#cite_note-45"><span class="cite-bracket">[</span>44<span class="cite-bracket">]</span></a></sup><sup id="cite_ref-46" class="reference"><a href="#cite_note-46"><span class="cite-bracket">[</span>45<span class="cite-bracket">]</span></a></sup>
</p>
<div class="mw-heading mw-heading2"><h2 id="Notes">Notes</h2></div>
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<li id="cite_note-15"><span class="mw-cite-backlink"><b><a href="#cite_ref-15">^</a></b></span> <span class="reference-text">The 420 is for "phases that might have played a significant role in Hadean geochemical processes"; there are also more than 100 rare minerals.<sup id="cite_ref-Hadean_6-1" class="reference"><a href="#cite_note-Hadean-6"><span class="cite-bracket">[</span>6<span class="cite-bracket">]</span></a></sup></span>
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<div class="mw-heading mw-heading2"><h2 id="References">References</h2></div>
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<div class="mw-heading mw-heading2"><h2 id="Further_reading">Further reading</h2></div>
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<ul><li><cite id="CITEREFAnbar2012" class="citation journal cs1">Anbar, A. D. (27 September 2012). "A Coevolutionary Tale". <i>Science</i>. <b>337</b> (6102): 1606. <a href="Bibcode_(identifier)" class="mw-redirect" title="Bibcode (identifier)">Bibcode</a>:<a rel="nofollow" class="external text" href="https://ui.adsabs.harvard.edu/abs/2012Sci...337.1606A">2012Sci...337.1606A</a>. <a href="Doi_(identifier)" class="mw-redirect" title="Doi (identifier)">doi</a>:<a rel="nofollow" class="external text" href="https://doi.org/10.1126%2Fscience.1224957">10.1126/science.1224957</a>. <a href="S2CID_(identifier)" class="mw-redirect" title="S2CID (identifier)">S2CID</a> <a rel="nofollow" class="external text" href="https://api.semanticscholar.org/CorpusID:85223436">85223436</a>.</cite></li>
<li><cite id="CITEREFBerardelli2008" class="citation news cs1">Berardelli, Phil (14 November 2008). <a rel="nofollow" class="external text" href="https://www.science.org/content/article/earths-minerals-evolved-too">"Earth's Minerals Evolved, Too"</a>. <i>Science</i>. AAAS<span class="reference-accessdate">. Retrieved <span class="nowrap">9 September</span> 2017</span>.</cite></li>
<li><cite id="CITEREFJames_Cleaves_IIMichalkova_ScottHillLeszczynski2012" class="citation journal cs1">James Cleaves II, H.; Michalkova Scott, Andrea; Hill, Frances C.; Leszczynski, Jerzy; Sahai, Nita; Hazen, Robert (2012). "Mineral–organic interfacial processes: potential roles in the origins of life". <i>Chemical Society Reviews</i>. <b>41</b> (16): <span class="nowrap">5502–</span>5525. <a href="Doi_(identifier)" class="mw-redirect" title="Doi (identifier)">doi</a>:<a rel="nofollow" class="external text" href="https://doi.org/10.1039%2Fc2cs35112a">10.1039/c2cs35112a</a>. <a href="PMID_(identifier)" class="mw-redirect" title="PMID (identifier)">PMID</a> <a rel="nofollow" class="external text" href="https://pubmed.ncbi.nlm.nih.gov/22743683">22743683</a>.</cite></li>
<li><cite id="CITEREFDeep_Carbon_Observatory" class="citation news cs1"><a href="Deep_Carbon_Observatory" title="Deep Carbon Observatory">Deep Carbon Observatory</a>. <a rel="nofollow" class="external text" href="https://web.archive.org/web/20181013073559/https://deepcarbon.net/feature/new-exhibit-opens-vienna-showcases-mineral-evolution-earth">"New Exhibit Opens in Vienna, Showcases Mineral Evolution on Earth"</a>. Archived from <a rel="nofollow" class="external text" href="https://deepcarbon.net/feature/new-exhibit-opens-vienna-showcases-mineral-evolution-earth">the original</a> on 13 October 2018<span class="reference-accessdate">. Retrieved <span class="nowrap">24 August</span> 2018</span>.</cite></li>
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<li><cite id="CITEREFHamilton2016" class="citation episode cs1">Hamilton, Doug (13 January 2016). <a rel="nofollow" class="external text" href="http://www.pbs.org/video/nova-lifes-rocky-start-pro/">"Life's rocky start"</a>. <i>Nova</i>. Season 43. Episode 3. PBS. <a rel="nofollow" class="external text" href="http://www.pbs.org/wgbh/nova/earth/life-rocky-start.html">Transcript</a><span class="reference-accessdate">. Retrieved <span class="nowrap">13 May</span> 2018</span>.</cite></li>
<li><cite id="CITEREFMann2017" class="citation news cs1">Mann, Adam (31 October 2017). <a rel="nofollow" class="external text" href="https://medium.com/@adammann930/what-mineral-evolution-tells-us-about-life-on-earth-and-beyond-7d9be193ea30">"What Mineral Evolution Tells Us About Life On Earth – And Beyond"</a>. <i>Medium</i><span class="reference-accessdate">. Retrieved <span class="nowrap">11 August</span> 2018</span>.</cite></li>
<li><cite id="CITEREFSaey2015" class="citation news cs1">Saey, Tina Hesman (16 February 2015). <a rel="nofollow" class="external text" href="https://web.archive.org/web/20180826054644/https://www.sciencenews.org/article/mineralogy%E2%80%99s-link-ecology-makes-earth-twin-unlikely">"Mineralogy's link to ecology makes an Earth twin unlikely"</a>. <i>Science News</i>. Archived from <a rel="nofollow" class="external text" href="https://www.sciencenews.org/article/mineralogy’s-link-ecology-makes-earth-twin-unlikely">the original</a> on 26 August 2018<span class="reference-accessdate">. Retrieved <span class="nowrap">24 August</span> 2018</span>.</cite></li>
<li><cite id="CITEREFVasconcelosMcKenzie2009" class="citation journal cs1">Vasconcelos, C.; McKenzie, J. A. (9 January 2009). "The Descent of Minerals". <i>Science</i>. <b>323</b> (5911): <span class="nowrap">218–</span>219. <a href="Doi_(identifier)" class="mw-redirect" title="Doi (identifier)">doi</a>:<a rel="nofollow" class="external text" href="https://doi.org/10.1126%2Fscience.1168807">10.1126/science.1168807</a>. <a href="PMID_(identifier)" class="mw-redirect" title="PMID (identifier)">PMID</a> <a rel="nofollow" class="external text" href="https://pubmed.ncbi.nlm.nih.gov/19131619">19131619</a>. <a href="S2CID_(identifier)" class="mw-redirect" title="S2CID (identifier)">S2CID</a> <a rel="nofollow" class="external text" href="https://api.semanticscholar.org/CorpusID:206517566">206517566</a>.</cite></li>
<li><cite class="citation news cs1"><a rel="nofollow" class="external text" href="https://www.economist.com/science-and-technology/2008/11/13/how-rocks-evolve">"How rocks evolve"</a>. <i>The Economist</i>. 13 November 2008<span class="reference-accessdate">. Retrieved <span class="nowrap">10 September</span> 2017</span>.</cite></li></ul>
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<div class="mw-heading mw-heading2"><h2 id="External_links">External links</h2></div>
<ul><li><cite class="citation web cs1"><a rel="nofollow" class="external text" href="https://rruff.info/mineral_list/locality.php?mineral_name=Abellaite">"Abellaite"</a>. <i>Mineral Evolution Database</i>.</cite></li></ul></div><!--htdig_noindex--><div><div class="zim-footer">
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